9-Phenyl-10H-acridinium trifluoromethanesulfonate

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9-Phenyl-10H-acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(19)H(14)N(+)·CF(3)SO(3) (-), the cations are linked to each other by very weak C-H⋯π inter-actions, while the cations and anions are connected by N-H⋯O, C-H⋯O and S-O⋯π inter-actions. The acridine ring system and the phenyl ring are oriented at an angle of 80.1 (1)° with respect to each other. The mean planes of adjacent acridine units are eithe...

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In the crystal structure of the title compound, C(14)H(12)NS(+)·CF(3)SO(3) (-), N-H⋯O hydrogen bonds link cations and anions into ion pairs. Inversely oriented ion pairs form stacks through multidirectional π-π inter-actions among the acridine units. The crystal structure features a network of C-H⋯O inter-actions among stacks and also long-range electrostatic inter-actions among ions. In the pa...

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In the title compound, C(19)H(15)NOS, the butterfly angle between the mean planes defined by the S, N and phenyl C atoms of the two wings of the phenothiazine unit is 23.4 (1)°. In the crystal, a supra-molecular two-dimensional arrangement arises from weak inter-molecular C-H⋯O inter-actions.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810040900